List of eutectic alloys

Eutectic alloys have two or more materials and have a eutectic composition. When a non-eutectic alloy solidifies, its components solidify at different temperatures, exhibiting a plastic melting range. Conversely, when a well-mixed, eutectic alloy melts, it does so at a single, sharp temperature.
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Eutectic alloys have two or more materials and have a eutectic composition. When a non-eutectic alloy solidifies, its components solidify at different temperatures, exhibiting a plastic melting range. Conversely, when a well-mixed, eutectic alloy melts, it does so at a single, sharp temperature.

Eutectic Alloy: A eutectic alloy is an alloy formed from two or more components that exhibits eutectic behavior. A eutectic alloy melts at a distinct temperature. Not all binary alloys form eutectic alloys. For example, gold-silver does not form a eutectoid, as the valence electrons are not compatible with super-lattice formation.

Table 3 outlines the most common eutectic alloys used for hermetic and/or vacuum packaging of IC, MEMS, and smart sensing devices, and their corresponding eutectic temperatures.

Eutectics are alloys of inorganics (mostly hydrated salts) or organics with a minimum-melting composition of two or more components, each of which melts and freezes and congruently forming a mixture of the component crystals during solidification [95].

Eutectic alloys are a type of high-entropy alloy that exhibit good castability and high mechanical strength. These alloys undergo an isothermal transformation called the eutectic reaction, which helps to reduce chemical segregation and shrinkage cavity.

The eutectic point is a unique temperature at which a combination of different substances melts or solidifies simultaneously. This temperature is the lowest possible melting point that the mixture can attain, lower than any of the substances’ individual melting points.

A eutectic mixture or system, on the other hand, is this particular combination of substances that have the characteristic of melting and solidifying at the eutectic point. In the correct proportions, the mixture components inhibit the crystallization phase of one another. These mixtures are interesting due to their uniform behavior, differing from most mixtures which have variable melting or solidifying ranges.

“Eutectic” comes from the Greek words “eu” meaning “well” or “good” and “teknē” meaning “art”, suggesting the mixtures have ‘good art’ or ‘well crafted’ behavior in their phase transitions. British scientist Frederick Guthrie coined the term in 1884.

If you are still confused about what is and is not a eutectic, remember that the defining characteristic of a eutectic mixture is that it has a melting point lower than any of its individual components. Therefore, by definition, the eutectic point cannot be higher than the melting point of one of the components. If a mixture does not exhibit this property, it is not considered a eutectic mixture. So, not all alloys or other mixtures are eutectics.

Whether or not a pair of substances forms a eutectic mixture depends primarily on the details of their phase diagram, which plots the state of the substances (solid, liquid, gas) under different temperatures and compositions. This is a complex question that depends on the specifics of the atomic or molecular interactions between the substances. However, there are several general factors that promote the formation of eutectic mixtures:

Remember that these factors can increase the likelihood of forming a eutectic mixture but do not guarantee it. Whether a eutectic mixture forms depends on the specifics of the system under consideration. Also, these factors primarily apply to eutectic alloys. Similar considerations apply to other types of eutectic mixtures as well.

Each diagram is marked with an arrow at the eutectic composition and indicating the current temperature (the start temperature in this case). The circle below the diagram shows a stylised representation of the alloy''s microstructure (here showing nothing of interest as the alloy is liquid).

Note that the alloy forms into "stripes" which are alternate layers of alpha and beta. These layers are often only of the order of 1 micron across and the reason that the eutectic forms in this way can be understood by considering the diffusion times required to form the solid. The "stripy" microstructure is known as lamellar microstructure.

These nucleating and growing regions of solid alloy will form grains. Grain boundaries occur where growing grains, which will be of differing orientations and from different nucleation sites, meet.

Further nucleation sites will continue to form within the liquid parts of the mixture. Remember, though, this happens over a very short time scale and with no further decrease in temperature. The eutectic composition solidifies, like a pure element, at a single temperature, not over a temperature range.

By considering tie lines and the phase diagram, it can be seen that beta has a decreasing proportion of A in it as the temperature decreases. Similarly the proportion of B in alpha decreases.

This means that even though the alloy is now solid, the composition of the stripes of alpha and beta must continue to change as it cools (to room temperature for example). Atoms of A and B will diffuse across these "stripes" to produce the equilibrium compositions of alpha and beta at a given temperature.

In regular eutectic, the two phases usually form a regular eutectic structure in the form of lamel or fiber. The two component phases of regular eutectic are mainly composed of metal to metal or metal to intermetallic compound (non-facet – non-facet phase). They have low melting entropy....

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About List of eutectic alloys

About List of eutectic alloys

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